PEG-20 Glyceryl Triisostearate CAS 86846-21-1

Premium Self-Emulsifying Emulsifier & Moisturizing Agent for Professional Makeup Removal and Cosmetic Formulations

CAS NO: 86846-21-1 Self-Emulsifying Cosmetic Grade

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Technical Deep Dive: The Chemistry and Functional Supremacy of PEG-20 Glyceryl Triisostearate (CAS NO.: 86846-21-1)

Within the rapidly evolving landscape of professional cosmetics formulation, the demand for high-performance, non-irritating, and multifunctional ingredients is at an all-time high. Consumers and brands alike are shifting towards minimal yet highly efficient routines. Among the essential raw materials driving this transformation is PEG-20 Glyceryl Triisostearate (CAS NO.: 86846-21-1), an exceptional self-emulsifying non-ionic surfactant, emulsifier, and emollient. Renowned for its superior ability to clear oil-based impurities while preserving the delicate skin barrier, this compound has become the industry gold standard for premium makeup removing formulations, including cleansing oils, balms, and emulsions.

1. Molecular Chemistry & Self-Emulsifying Mechanism

PEG-20 Glyceryl Triisostearate is a triester of glycerin, branched isostearic acid, and polyethylene glycol (PEG). The structure features a hydrophobic core of branched isostearic acid chains and a hydrophilic tail formed by 20 units of ethylene oxide (EO). This unique architecture provides a perfectly balanced Hydrophilic-Lipophilic Balance (HLB) value of approximately 10.0 to 11.0. This mid-range HLB makes it an ideal oil-in-water (O/W) emulsifier that is highly capable of forming spontaneous microemulsions when contact is made with water.

Unlike linear fatty acid esters, the branched C18 structure of isostearic acid inhibits crystallization, keeping the raw material liquid and exceptionally stable across a wide temperature range. In formulation, it acts as a coupling agent. When applied to dry skin, the hydrophobic lipid sections dissolve makeup, sebum, and sunscreen residues. Upon rinsing, the hydrophilic PEG-20 chains immediately wrap around these oil droplets, forming a fine, milky emulsion that washes away completely without leaving a greasy film or stripping the skin’s natural lipid barrier.

Physicochemical Property Standard Specification Value Significance in Cosmetics Formulation
Chemical Name PEG-20 Glyceryl Triisostearate International Nomenclature of Cosmetic Ingredients (INCI)
CAS Number 86846-21-1 Global inventory registration registry identity
HLB Value 10.0 - 11.5 Balanced self-emulsification and rinse-off profile
Appearance (25°C) Pale yellow transparent liquid to viscous paste Easy handling, minimal odor, and low color interference
Acid Value (mg KOH/g) ≤ 10.0 High chemical stability and compatibility with skin pH
Moisture Content (%) ≤ 1.0 Prevents microbial activity and degradation of active formulations

2. Key Performance Attributes in Cosmetics & Cleansers

Unrivaled Emulsifying Power

Heavy foundations, waterproof mascaras, and silicone-based sunscreens are designed to resist water. Removing them requires a surfactant with strong lipophilic affinity. PEG-20 Glyceryl Triisostearate interacts directly with waxy and polymer residues, liquefying them instantly on contact. Because it is self-emulsifying, it does not require vigorous rubbing, mitigating the risk of mechanical skin irritation.

Inherent Moisture Retention & Skin Conditioning

Many traditional anionic surfactants cleanse at the expense of skin barrier integrity, leading to elevated Trans-Epidermal Water Loss (TEWL). As a non-ionic agent, PEG-20 Glyceryl Triisostearate does not disrupt the stratum corneum structure. It leaves behind an ultra-light, breathable moisturizing film that conditions the skin, making it highly suitable for dry, sensitive, or compromised skin types.

Excellent Formulation Compatibility

It displays remarkable chemical compatibility with a wide array of polar and non-polar cosmetic oils, including Caprylic/Capric Triglycerides (GTCC), mineral oils, synthetic esters, and natural plant oils (such as jojoba and sweet almond oils). It remains stable in formulations containing antioxidants, preservatives, and essential oils, providing formulators with vast creative flexibility.

3. Strategic Localization & International Compliance

For multinational cosmetic brands, ensuring the regulatory compliance of raw materials is vital. Our production processes for PEG-20 Glyceryl Triisostearate (CAS 86846-21-1) strictly align with modern global regulations:

  • REACH Compliance: Fully registered under the European Chemicals Agency (ECHA) standards, ensuring safe trade and application across EU member states.
  • US FDA VCRP & CSAR: Compliant with the Cosmetic Supervision and Administration Regulation (CSAR) of China and the FDA guidelines of the United States.
  • Sustainable Sourcing & RSPO: We prioritize raw material supply lines that support sustainable palm oil production and ecological balance.
  • Halal & Kosher Readiness: Our manufacturing plant operates under conditions compatible with Halal and Kosher certification requirements.

4. Global Procurement & Supply Chain Excellence of China Factories

As a leading Chinese daily chemical manufacturer, Suzhou Yuantairun Chemical Co., Ltd. represents the standard of chemical manufacturing efficiency. Operating from the industrial chemical cluster of Suzhou, Jiangsu Province, we integrate state-of-the-art ethoxylation and esterification technology with localized cost structures. This strategic positioning offers global cosmetics buyers several key benefits:

  • Scalability and Bulk Capacity: Continuous-flow reactors allow us to scale production up to thousands of metric tons per year, ensuring stable pricing and contract safety.
  • Strict Quality Assurance (QA): Each batch undergoes rigorous testing including Gas Chromatography (GC), Acid Value assays, and Trace Heavy Metal analyses.
  • Optimal Logistics & Delivery: Close proximity to major global ports (such as Shanghai and Ningbo) facilitates efficient packing, customs handling, and rapid worldwide shipping.

Quick Contact

Suzhou Yuantairun Chemical Co., Ltd. is ready to support your formulation requirements with custom samples and expert laboratory advice.


Key Applications:

  • Cleansing Oils
  • Cosmetic Cleansing Balms
  • Facial Wash & Wipes
  • Sensitive Skin Formulations
  • O/W Emulsion Creams
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2010
Established Year
7,000+
Cooperative Partners
99.9%
Quality Pass Rate
100%
Global REACH Compliant

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Premium Cleansing Oils

Role: Core Self-Emulsifying Agent & Emollient

Recommended Dosage: 10% - 15%

Formulated alongside Caprylic/Capric Triglyceride (GTCC) and natural oils. Provides a clear, stable liquid system that completely emulsifies on contact with warm water, rinsing clean with zero greasy residue.

Cleansing Balms

Role: Emulsifier & Texture Modifier

Recommended Dosage: 8% - 12%

Helps structure solid-to-oil melting balms. Improves spreadability and facilitates rapid, smooth phase transformation from balm to milk when rinsed, ensuring absolute user satisfaction.

Mild Amino Acid Facial Cleansers

Role: Super-fatting Agent & Gentle Surfactant

Recommended Dosage: 1% - 3%

Reduces irritation profiles in mild amino acid cleansers. Re-fatting properties ensure the skin maintains optimal moisture levels and does not feel dry or tight post-rinse.

Washing Powder & Heavy-Duty Cleaners

Leveraging our wide range of anionic and nonionic surfactants such as SLES and APG, our formulations support heavy soil and oil removal across industrial and home laundry environments, offering deep cleaning action and controlled sudsing.

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By utilizing advanced cationic systems like Cetrimonium Chloride alongside conditioning polymers, we support brands in creating hair care and fabric softeners that deposit uniformly, reduce static charge, and improve tactile softness.

Frequently Asked Questions

Get professional insights from our R&D chemists regarding the application, safety, and supply of PEG-20 Glyceryl Triisostearate.

What makes PEG-20 Glyceryl Triisostearate the preferred choice over standard polysorbates?
PEG-20 Glyceryl Triisostearate provides a superior sensory profile, lower skin irritation indicators, and excellent self-emulsifying metrics. Standard polysorbates can sometimes leave a sticky, waxy residue and are prone to causing skin tightness or foaming excessively in rinse-off systems. Our CAS 86846-21-1 material ensures a clean rinse-off with zero residual film, leaving the skin feeling moisturized, supple, and fresh.
What is the exact HLB value and temperature stability of this ingredient?
The Hydrophilic-Lipophilic Balance (HLB) value of our PEG-20 Glyceryl Triisostearate is approximately 10.5. Due to the branched structure of its constituent isostearic acid tails, it is highly resistant to low-temperature crystallization. This enables finished cleansing oils and balms to remain transparent and stable without clouding or splitting, even during cold winter transportation or storage.
Is this ingredient non-comedogenic and safe for acne-prone skin formulations?
Yes, PEG-20 Glyceryl Triisostearate is characterized as non-comedogenic. Because it completely emulsifies with water and lifts oil-based blockages from the hair follicles, it does not leave a heavy occlusive layer that could clog pores. It is highly recommended for oil control cleansers and sensitive skin formulations.
What global compliance certifications can you provide with your shipments?
Suzhou Yuantairun Chemical provides comprehensive documentation with every delivery batch. This includes a Certificate of Analysis (COA), Safety Data Sheets (SDS) matching regional regulations, REACH registration confirmations for European buyers, and declarations of compliance with cosmetic raw material safety standards (CSAR, FDA, EC 1223/2009).
What is the typical lead time for international bulk shipments?
Our typical production and packing lead time for standard bulk volumes ranges from 7 to 15 days from order confirmation. Thanks to our location near the ports of Shanghai and Ningbo, transit and shipping times are optimized to minimize container handling delays.

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Ideal for retail commercial settings, shopping malls, restaurants, and medical environments, featuring mild, skin-friendly active systems.

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